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OCR GCSE Chemistry B · J258
OCR J258 Check the specification (PDF) (opens in a new tab)
Explain the vast array of organic compounds based on carbon's ability to form families of similar compounds, chains, and rings.
Organic compounds are based on carbon. Some occur naturally, while others are made synthetically. Carbon can form four covalent bonds, and a carbon atom can bond to another carbon atom. Repeating those carbon–carbon bonds builds a carbon skeleton that can be short or long, straight or branched. A chain can also join back on itself to form a ring. Hydrogen and other atoms can attach to the skeleton, creating still more possibilities.
Compare a straight chain of four carbon atoms with a branched arrangement of four carbon atoms. Both use the same number of carbon atoms, but the atoms are connected differently. Rings add another kind of arrangement. These different structures help explain why carbon gives rise to such a vast array of compounds rather than just a few.
Carbon atoms can connect in straight chains, branched chains and rings. Hydrogen atoms are omitted from these simplified skeletons.
The many compounds are not all unrelated. Chemists group compounds with similar structures and chemical properties into families, called homologous series. For example, methane (), ethane () and propane () are members of the alkane family. Moving from one to the next adds one carbon atom and two hydrogen atoms—a unit—while keeping the same general bonding pattern. Members therefore have similar chemical behaviour, although properties such as boiling point change as the molecules get larger.
Carbon's ability to build varied chains and rings creates many possible structures; grouping related structures into families makes that variety easier to understand. The same bonding possibilities underpin carbon compounds found in living things and those made in laboratories.
Carbon forms four covalent bonds and bonds to itself. Its atoms can form chains, branched chains and rings, allowing a vast range of natural and synthetic organic compounds.
Related organic compounds form homologous series. The alkanes are one example: successive members differ by and have similar chemical properties.
Link the large number of organic compounds to all three ideas: carbon forms chains, rings and families of similar compounds.
A homologous series is a family of related compounds, not simply any set of molecules containing carbon.
In a structural drawing, check that each carbon atom has four covalent bonds in total.
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Organic compound
A compound based on carbon, whether it occurs naturally or is made synthetically.
Carbon skeleton
A framework of carbon atoms joined by covalent bonds, which may form a chain, branches or a ring.
Homologous series
A family of organic compounds with similar structures and chemical properties; successive members differ by a repeating unit.
Put your knowledge into practice — try past paper questions for Chemistry B
Organic compound
A compound based on carbon, whether it occurs naturally or is made synthetically.
Carbon skeleton
A framework of carbon atoms joined by covalent bonds, which may form a chain, branches or a ring.
Homologous series
A family of organic compounds with similar structures and chemical properties; successive members differ by a repeating unit.