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Edexcel GCSE Chemistry · 1CH0
Edexcel 1CH0 · 6.12 Check the specification (PDF) (opens in a new tab)
A halogen is an element in Group 7, such as chlorine or bromine. A halide ion is a negatively charged particle formed from a halogen: chloride is Cl⁻ and bromide is Br⁻. When chlorine is added to an aqueous solution of sodium bromide, chlorine displaces bromine:
The sodium ions are present before and after the reaction but do not change. Leaving them out makes it easier to see the reacting particles:
Each bromide ion loses one electron. Two bromide ions therefore lose two electrons and form one bromine molecule:
Bromide ions are oxidised because oxidation is loss of electrons. The chlorine molecule gains those two electrons, forming two chloride ions:
Chlorine is reduced because reduction is gain of electrons. The equations are called half-equations: one shows the electron loss and the other shows the electron gain. Together they account for the two electrons transferred, which cancel when the half-equations are combined.
Oxidation and reduction occur together here: electrons lost by bromide ions are gained by chlorine. That makes the displacement a redox reaction. The same reasoning applies when a more reactive halogen displaces another halogen from a halide solution: identify which halide ions lose electrons, and which halogen molecules gain them.
A halide ion loses electrons to form a halogen molecule: it is oxidised. The displacing halogen molecule gains electrons to form halide ions: it is reduced. Both changes occur together.
For :
The electrons lost equal the electrons gained; spectator ions do not take part.
Identify the reacting particles, not just the compounds: in chlorine reacting with sodium bromide, Br⁻ is oxidised and Cl₂ is reduced; Na⁺ is unchanged.
In a half-equation, electrons on the right show oxidation; electrons on the left show reduction.
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Oxidation
Loss of electrons by a particle.
Reduction
Gain of electrons by a particle.
Redox reaction
A reaction in which oxidation and reduction happen together through electron transfer.
Halide ion
A negatively charged ion formed when a halogen atom gains an electron, such as Br⁻.
Displacement reaction
A reaction in which a more reactive element takes the place of a less reactive element in a compound.
Put your knowledge into practice — try past paper questions for Chemistry
Oxidation
Loss of electrons by a particle.
Reduction
Gain of electrons by a particle.
Redox reaction
A reaction in which oxidation and reduction happen together through electron transfer.
Halide ion
A negatively charged ion formed when a halogen atom gains an electron, such as Br⁻.
Displacement reaction
A reaction in which a more reactive element takes the place of a less reactive element in a compound.